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dc.contributor.authorMinić, Aleksandra
dc.contributor.authorNovaković, Slađana
dc.contributor.authorBogdanović, Goran
dc.contributor.authorBugarinović, Jovana
dc.contributor.authorPešić, Marko
dc.contributor.authorTodosijević, Anka
dc.contributor.authorIlić Komatina, Danijela
dc.contributor.authordam, Ivan
dc.contributor.authorStevanović, Dragana
dc.date.accessioned2022-09-26T10:00:22Z
dc.date.available2022-09-26T10:00:22Z
dc.date.issued2020-02
dc.identifier.urihttps://platon.pr.ac.rs/handle/123456789/663
dc.description.abstractThe stereochemical phenomenon that arises from hindered rotation around bonds in nonplanar molecules is termed the atropoisomerism. During our previous work we noted the presence of this kind of isomerism in 1-aryl-4-ferrocenyl-3-phenyltetrahydropyrimidin-2(1H)-ones obtained from ortho-substituted 3-(arylamino)-1-ferrocenylpropan-1-ols. Inspired by an interesting biological/medical features of six-membered cyclic ureas and characteristic of “atropoisomers - things that rotate”, herein we present an easy performable synthesis and full characterisation of novel atropoisomeric ferrocene-containing six-membered cyclic ureas. In addition, we successfully determined the crystal structure of two atropoisomers for the same compound. Molecular structural properties and intermolecular interactions of these two structures have been compared and analyzed in detail. Interesting, it has been found that these two isomers although quite similar in conformation and geometrical parameters, form very different crystal packing.en_US
dc.language.isoen_USen_US
dc.publisherPolyhedronen_US
dc.rightsАуторство-Некомерцијално-Без прерада 3.0 САД*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/us/*
dc.titleSynthesis and structural characterizations of novel atropoisomeric ferrocene-containing six-membered cyclic ureasen_US
dc.title.alternativePolyhedronen_US
dc.typeclanak-u-casopisuen_US
dc.description.versionpublishedVersionen_US
dc.identifier.doi10.1016/j.poly.2019.114316
dc.citation.volume177
dc.subject.keywordsFerrocenesen_US
dc.subject.keywordsAtropoisomerismen_US
dc.subject.keywordsCrystal structureen_US
dc.type.mCategoryM22en_US
dc.type.mCategoryopenAccessen_US
dc.type.mCategoryM22en_US
dc.type.mCategoryopenAccessen_US


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Ауторство-Некомерцијално-Без прерада 3.0 САД
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